Recovery of potassium salt by acidification of crude glycerol derived from biodiesel production

Abstract

Crude glycerol (CG) is a major byproduct of biodiesel production. Most of it cannot be utilized due to major impurities. The CG generally contains alkalis, which generate the residual salts in a series of its purification stages. This study aims to obtain the optimum process conditions and acid molar ratio to produce a higher potassium salt yield while improving the purity of glycerol by a simple acidification procedure. The CG was obtained from the transesterification of palm oil using a catalyst based on potassium carbonate. A phosphoric acid (85%) is utilized at various molar ratios and the process temperature is 60-80 °C. The strong acid was slowly added to the CG and heated for 30 minutes with a mixing speed of 250 rpm. The optimum acidification process occurred at a temperature of 70 °C with a molar crude glycerol ratio to phosphoric acid of 1 : 0.5. The glycerol purity was increased from 43.3% to 67.63% (w/w). It effectively obtains a potassium phosphate salt with a yield of 6.78%. The functional group infrared (IR) and X-ray fluorescence (XRF) spectra identified the salt residue as potassium dihydrogen phosphate (KH2PO4). This is composed predominantly of potassium oxide (K2O) and phosphorus pentoxide (P2O5), 50% and 47.9%, respectively.