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Vanadium-catalyzed isomerization of cyclopropanemethanols to homoallylic alcohols involving C-C bond cleavage

Chemistry Letters (2005) 34(3) 380-381
DOI: 10.1246/cl.2005.380
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Abstract

Some vanadium compounds work as effective catalysts for isomerization of cyclopropanemethanols to the corresponding homoallylic alcohols. This reaction may proceed via [3,3]sigmatropic rearrangement involving an oxovanadium cyclopropanemethanolate accompanied by the C-C bond cleavage. Copyright © 2005 The Chemical Society of Japan.

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Maeda, Y., Nishimura, T., & Uemura, S. (2005). Vanadium-catalyzed isomerization of cyclopropanemethanols to homoallylic alcohols involving C-C bond cleavage. Chemistry Letters, 34(3), 380–381. https://doi.org/10.1246/cl.2005.380

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