Detecting fludioxonil residues in brown rice and rice straw using gas chromatography-nitrogen phosphorus detector

Abstract

In the present study, brown rice was steeped in 20 % wettable powder fludioxonil for 24 h, subsequently germinated, and transplanted in paddy fields. The harvested rice was tested at 156 days to detect residue levels using gas chromatography-nitrogen phosphorus detector. Validation was carried out to assess the following parameters: linearity, limit of detection and limit of quantitation (LOQ), recovery, and storage stability. Using matrix-matched calibrations, the determination coefficients were >0.999 in both matrices. Mean recoveries were 73.5–101.0 % with relative standard deviations <10 % in both matrices. The LOQ (0.006 mg/kg) was lower than the maximum residue limit (MRL = 0.02 mg/kg) set by the Ministry of Food and Drug Safety, Republic of Korea. The developed method was applied successfully, and no residues were detected in field-incurred rice and/or rice straw samples.