Abstract
We time resolved the CO ligand transfer process in the bimetallic active site of cytochrome c oxidase, using mid-infrared chirped-pulse upconversion to observe the full vibrational signature of Fe-CO bond breaking and CuB-CO bond formation.
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Treuffet, J., Kubarych, K. J., Lambry, J. C., Pilet, E., Masson, J. B., Martin, J. L., … Alexandrou, A. (2009). Direct observation of ligand transfer and bond formation in cytochrome c oxidase using mid-infrared chirped-pulse upconversion. In Springer Series in Chemical Physics (Vol. 92, pp. 541–543). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-540-95946-5_175
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