Room-temperature bulk plasticity and tunable dislocation densities in KTaO3

Abstract

We report room-temperature bulk plasticity mediated by dislocations in single-crystal cubic potassium tantalate oxide (KTaO3), contrasting the conventional knowledge that single-crystal KTaO3 is susceptible to brittle fracture. A mechanics-based combinatorial experimental approach using cyclic Brinell indentation, scratching, and uniaxial bulk compression consistently demonstrates room-temperature dislocation plasticity in KTaO3 from the mesoscale to the macroscale. This approach also delivers tunable dislocation densities and plastic zone size. Scanning transmission electron microscopy analysis underpins the activated slip system to be <110> {1 (Formula presented.) 0}. Given the growing significance of KTaO3 as an emerging electronic oxide and the increasing interest in dislocations for tuning the physical properties of oxides, our findings are expected to trigger synergistic research interest in KTaO3 with tunable dislocation densities.