3-Methyl-4-{(E)-[4-(methylsulfanyl)benzylidene]amino}-1H-1,2, 4-triazole-5(4H)-thione

Abstract

In the title molecule, C11H12N4S 2, the dihedral angle between the triazole and benzene rings is 21.31 (5)°. A weak intramolecular C - H⋯S hydrogen bond generates an S(6) ring motif. In the crystal, pairs of N - H⋯S hydrogen bonds form inversion dimers. In addition, π-π interactions are observed between the benzene rings, with a centroid-centroid separation of 3.7599 (11) Å.