Abstract
The C-S bond is formed to a greater extent than the C-O bond in the transition state of the [4+2] cycloaddition of S02 to dimethylidenecyclohexane (see scheme). Both deuterium isotope effects and quantum calculations lead to this conclusion.
Author supplied keywords
Cite
CITATION STYLE
APA
Monnat, F., Vogel, P., Meana, R., & Sordo, J. A. (2003). Equilibrium and kinetic deuterium isotope effects on the hetero-Diels-Alder addition of sulfur dioxide. Angewandte Chemie - International Edition, 42(33), 3924–3927. https://doi.org/10.1002/anie.200351732
Register to see more suggestions
Mendeley helps you to discover research relevant for your work.
Already have an account? Sign in
Sign up for free