Free radical and RAFT polymerization of vinyl esters in metal-organic-frameworks

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Abstract

Free radical and RAFT polymerization of vinyl esters with different molecular dimensions are conducted in the nanochannels of metal-organic-frameworks (MOFs). The combination of MOFs with the RAFT technique enables the synthesis of highly isotactic poly(vinyl ester)s with a controlled molecular weight and narrow molecular weight distribution, and stereocontrolled isotactic-block-atactic vinyl ester block copolymers.

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CITATION STYLE

APA

Hwang, J., Lee, H. C., Antonietti, M., & Schmidt, B. V. K. J. (2017). Free radical and RAFT polymerization of vinyl esters in metal-organic-frameworks. Polymer Chemistry, 8(40), 6204–6208. https://doi.org/10.1039/c7py01607g

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