Polymeric 2,5-Dihydroxy-l,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+)

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Abstract

The isotypic compounds Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) form infinite net-like layers. The transition metal ion is coordinated octahedrally. The dianion of 2,5-dihydroxy-l,4-benzoquinone, consisting of two allyl systems interlinked by two long C—C distances (152—153 pm), acts as a chelating ligand. Adjacent layers are connected by hydrogen bonds. The stacking sequence of these layers, ••.AAA., leads to channels, which are filled by hydrated Na+ ions. The Na+ ions are coordinated in a distorted octahedral fashion, with neighbouring octahedra sharing common faces. © 1986, Verlag der Zeitschrift für Naturforschung. All rights reserved.

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Weiss, A., Riegler, E., & Robl, C. (1986). Polymeric 2,5-Dihydroxy-l,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+). Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences, 41(12), 1501–1505. https://doi.org/10.1515/znb-1986-1204

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