Is polymorphism caused by molecular conformational changes?

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Abstract

The possibility that polymorphism is connected with variations of molecular conformations within a unit cell is explored graphically and numerically. The conclusion is that no direct relationship exists between one and the other because polymorphic crystals are found, equally frequently, in which the conformations of their molecules agree almost exactly, or agree somewhat, or display large differences. © 2008 Springer.

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Bernal, I. (2008). Is polymorphism caused by molecular conformational changes? In Models, Mysteries and Magic of Molecules (pp. 137–165). Kluwer Academic Publishers. https://doi.org/10.1007/978-1-4020-5941-4_6

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