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Highly Enantioselective Hiyama Cross-Coupling via Rh-Catalyzed Allylic Arylation of Racemic Allyl Chlorides

Organometallics (2019) 38(20) 3991-3995
DOI: 10.1021/acs.organomet.9b00197
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Abstract

Highly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cyclic allyl products and is compatible with heterocyclic allyl chloride electrophiles.

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APA

González, J., Schäfer, P., & Fletcher, S. P. (2019). Highly Enantioselective Hiyama Cross-Coupling via Rh-Catalyzed Allylic Arylation of Racemic Allyl Chlorides. Organometallics, 38(20), 3991–3995. https://doi.org/10.1021/acs.organomet.9b00197

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