Physical, chemical and geotechnical characterization of wet flue gas desulfurization gypsum and its potential application as building materials

Abstract

In South Africa, coal represents the primary source of energy used for electricity generation. Coal power plants use the wet flue gas desulfurization (WFGD) process to remove sulfur dioxide (SO2) from their flue gas. However, this technology produces a large amount of synthetic gypsum, resulting in waste disposal and environmental pollution. This study investigated the physical, chemical and geotechnical properties of WFGD gypsum and its potential application to develop cement-free bricks. WFGD gypsum was collected from a coal power plant in South Africa. It was found that the principal oxides of WFGD gypsum were sulfur trioxide (SO3) and calcium oxide (CaO), which represented more than 90% of the total weight. Calcium sulfate (CaSO4) and calcium di aluminate (CA2) were the predominant minerals in the raw material. The density of the WFGD gypsum was 2.43 g/cm3. The maximum dry density and optimum moisture content values were 1425 kg/m3 and 18.5%, respectively. WFGD gypsum had a liquid limit of 51% but did not display any plasticity characteristics. The optimum curing temperature of gypsum bricks was 40◦ C. WFGD gypsum-based bricks exhibited compressive strength of up to 2.3 MPa and a density of about 28% less than that of typical clay bricks. Additionally, there was no significant decrease in compressive strength after seven wet/dry cycles. These results show that WFGD gypsum could be used to produce lightweight building materials with low strength requirements.