Density functional study on benzene, toluene, ethylbenzene and xylene adsorptions on ZnO(100) surface

9Citations
Citations of this article
16Readers
Mendeley users who have this article in their library.

Abstract

We study the interaction between benzene, toluene, ethylbenzene and xylene (BTEX) molecules with ZnO(100) surface by means of density functional theory-based calculations. We find that these interactions result in the physical adsorptions of BTEX gases with adsorption distances larger than 2 Å. These adsorptions are governed by the van der Waals interaction instead of the covalent interaction. We also find that the trend of the strength of BTX adsorptions on ZnO(100) surface < < is in line with the experimental trend of sensitivity of ZnO material towards BTX gases (benzene < tolune < xylene). We explain this relation by using one of the sensing mechanism within the ionosorption model. By using this relation, we also predict that the response of ZnO towards ethylbenzene will be similar to the response towards toluene since these two molecules have similar adsorption energies on ZnO(100) surface.

Cite

CITATION STYLE

APA

Nugraha, Saputro, A. G., Agusta, M. K., Akbar, F. T., & Pramudya, A. D. (2019). Density functional study on benzene, toluene, ethylbenzene and xylene adsorptions on ZnO(100) surface. Molekul, 14(1), 37–47. https://doi.org/10.20884/1.jm.2019.14.1.501

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free