Adsorption Isotherm of Cr(VI) Using Mg/Al Hydrotalcite with Molar Ratio 2:1

  • Wiyantoko B
  • Kurniawati P
  • Purbaningtias T
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Abstract

ABSTRAK Hidrotalsit merupakan material yang digunakan pada beragam aplikasi salah satunya sebagai adsorben logam Cr(VI). Material hidrotalsit disintesis menggunakan metode kopresipitasi dengan bahan dasar garam Al(NO 3) 3 .9H 2 O dan Mg(NO 3) 2 .6H 2 O. Penelitian ini bertujuan untuk mengetahui pengaruh konsentrasi awal logam Cr(VI) serta isoterm adsorpsi yang sesuai untuk adsorpsi logam Cr(VI) oleh Mg/Al hidrotalsit dengan waktu kontak 180 menit.Konsentrasi awal logam Cr(VI) yaitu 675 mg/L dengan kapasitas adsorpsi sebesar 55,57 mg/g. Studi isoterm adsorpsi dianalisis menggunakan model isoterm Langmuir dan Freundlich. Berdasarkan hasil analisis adsorpsi logam Cr(VI) oleh Mg/Al hidrotalsit mengikuti model isoterm Langmuir dengan koefisen determinasi adalah 0,997. Kata-kataKunci : adsorpsi, Mg/Al hidrotalsit, isoterm adsorpsi ABSTRACT Hydrotalcite is a material which is used in various application and one of them as an adsorbent of Cr(VI). Hydrotalcite was synthesized using co-precipitation method with Al(NO 3) 3 .9H 2 O and Mg(NO 3) 2 .6H 2 O as raw materials. This research aim to study the initial concentration and adsorption isotherm of Cr(VI) by using Mg/Al hydrotalcite in 180 minutes contact time. The Optimum initial concentration of Cr(VI) was 675 mg/L with 55,57 mg/g adsorption capacity. Isotherm adsorption was studied using Langmuir and Freundlich model. Based on the result, the adsorption of Cr(VI) fitted well with Langmuir isotherm model by 0,997 coefficient of determination.

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Wiyantoko, B., Kurniawati, P., & Purbaningtias, T. E. (2014). Adsorption Isotherm of Cr(VI) Using Mg/Al Hydrotalcite with Molar Ratio 2:1. Jurnal Eksakta, 14(1), 20–26. https://doi.org/10.20885/eksakta.vol14.iss1.art2

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