Abstract
Disilver(I) palladium(II) diphosphate, Ag2PdP2O7, is isotypic with Na2PdP2O7. It consists of infinite diphosphato-pallad-ate(II) [Pd(P2O7)2/2] 2- ribbons with the PdII ion in an almost square-planar coordination ( symmetry) and the P2O7 group exhibiting 2 symmetry. The [Pd(P2O7)2/2]2- ribbons are linked by distorted [AgO6] octa-hedra. 31P-MAS NMR studies on Ag2PdP2O7 are in accordance with one independent site for phospho-rus; its isotropic chemical shift iso = 21.5 p.p.m. is similar to that of Pd2P2O7. © 2008.
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CITATION STYLE
Panagiotidis, K., & Glaum, R. (2008). Agμ22dPμ2O7. Acta Crystallographica Section E: Structure Reports Online, 64(12). https://doi.org/10.1107/S1600536808038518
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