Probing columnar discotic liquid crystals by EPR spectroscopy with a rigid-core nitroxide spin probe

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Abstract

Discotics studied by EPR: The application of EPR spectroscopy to columnar discotic liquid crystals using a novel rigid-core nitroxide spin probe (see picture) is possible. EPR spectra measured at different temperatures across three phases of hexakis(n-hexyloxy)triphenylene show a strong sensitivity to the phase composition, molecular rotational dynamics, and columnar order. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Gopee, H., Cammidge, A. N., & Oganesyan, V. S. (2013). Probing columnar discotic liquid crystals by EPR spectroscopy with a rigid-core nitroxide spin probe. Angewandte Chemie - International Edition, 52(34), 8917–8920. https://doi.org/10.1002/anie.201303194

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