The Vital Importance of Prior Information for the Decomposition of Ion Scattering Spectroscopy Data

  • Fischer R
  • von der Linden W
  • Dose V
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Abstract

The ubiquitous spectroscopic problem of decomposing overlapping lines is solved for ion scattering spectroscopy employing Maximum Entropy. The chosen example of Pd adsorption on a Ru surface is particularly challenging because 13 partially overlapping isotopes contribute to the total scattering signal. Proper decomposition using appropriate prior information enables accurate coverage determination.

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Fischer, R., von der Linden, W., & Dose, V. (1996). The Vital Importance of Prior Information for the Decomposition of Ion Scattering Spectroscopy Data. In Maximum Entropy and Bayesian Methods (pp. 31–40). Springer Netherlands. https://doi.org/10.1007/978-94-009-0107-0_4

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