Nitrogen-carbon bond formation from N2 and CO2 promoted by a hafnocene dinitrogen complex yields a substituted hydrazine

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Abstract

(Chemical Equation Presented) Hafnocene and hydrazine: The addition of two equivalents of carbon dioxide to the hafnocene dinitrogen complex 1 proved effective for the formation of nitrogen-carbon bonds directly from N2 and CO2. Subsequent treatment of 2 with Me3Sil liberated the dicarboxylated silyl-substituted hydrazine 3. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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Bernskoetter, W. H., Lobkovsky, E., & Chirik, P. J. (2007). Nitrogen-carbon bond formation from N2 and CO2 promoted by a hafnocene dinitrogen complex yields a substituted hydrazine. Angewandte Chemie - International Edition, 46(16), 2858–2861. https://doi.org/10.1002/anie.200604099

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