Total synthesis of (-)-(7S,10R)-calamenene and (-)-(7S,10R)-2- hydroxycalamenene by use of a ring-closing metathesis reaction. A comparison of the cis- and trans-isomers

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Abstract

The title compounds have been synthesized starting from l-menthone by application of a ring-closing metathesis reaction to confirm their reported absolute and relative stereochemistry. Comparisons of the NMR spectra and specific rotations are also discussed.

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CITATION STYLE

APA

Nakashima, K., Imoto, M., Sono, M., Tori, M., Nagashima, F., & Asakawa, Y. (2002). Total synthesis of (-)-(7S,10R)-calamenene and (-)-(7S,10R)-2- hydroxycalamenene by use of a ring-closing metathesis reaction. A comparison of the cis- and trans-isomers. Molecules, 7(7), 517–527. https://doi.org/10.3390/70700517

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