Total synthesis of (-)-(7S,10R)-calamenene and (-)-(7S,10R)-2- hydroxycalamenene by use of a ring-closing metathesis reaction. A comparison of the cis- and trans-isomers

Katsuyuki Nakashima; Masashi Imoto; Masakazu Sono; Motoo Tori; Fumihiro Nagashima; Yoshinori Asakawa

Journal ArticleOPEN ACCESS

Total synthesis of (-)-(7S,10R)-calamenene and (-)-(7S,10R)-2- hydroxycalamenene by use of a ring-closing metathesis reaction. A comparison of the cis- and trans-isomers

Nakashima K
Imoto M
Sono M
et al.

Molecules (2002) 7(7) 517-527

DOI: 10.3390/70700517

18Citations

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Abstract

The title compounds have been synthesized starting from l-menthone by application of a ring-closing metathesis reaction to confirm their reported absolute and relative stereochemistry. Comparisons of the NMR spectra and specific rotations are also discussed.

Author supplied keywords

Absolute configuration
Calamenene
Hydroxycalamenene
Ring closing metathesis
Sesquiterpene

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CITATION STYLE

APA

Nakashima, K., Imoto, M., Sono, M., Tori, M., Nagashima, F., & Asakawa, Y. (2002). Total synthesis of (-)-(7S,10R)-calamenene and (-)-(7S,10R)-2- hydroxycalamenene by use of a ring-closing metathesis reaction. A comparison of the cis- and trans-isomers. Molecules, 7(7), 517–527. https://doi.org/10.3390/70700517

Total synthesis of (-)-(7S,10R)-calamenene and (-)-(7S,10R)-2- hydroxycalamenene by use of a ring-closing metathesis reaction. A comparison of the cis- and trans-isomers

Abstract

Author supplied keywords

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