Mössbauer study of modified iron-molybdenum catalysts for methanol oxidation

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Abstract

The preparation and catalytic properties of mixed Fe-Mo-W catalysts toward methanol oxidation are investigated. Mössbauer spectroscopy, X-ray diffraction and chemical studies revealed the formation of two types of solid solutions with compositions Fe2(MoxW1-xO 4)3 and (MoxW1-x)O3. The solid solutions formed are characterized by high activity and selectivity upon methanol oxidation and are of interest in view of their practical application. Sodium-doped iron-molybdenum catalysts are also investigated and the NaFe(MoO4)2 formation was established. © 2010 IOP Publishing Ltd.

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Ivanov, K. I., Mitov, I. G., Krustev, S. V., & Boyanov, B. S. (2010). Mössbauer study of modified iron-molybdenum catalysts for methanol oxidation. In Journal of Physics: Conference Series (Vol. 217). Institute of Physics Publishing. https://doi.org/10.1088/1742-6596/217/1/012046

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