Can surface-transfer doping and UV irradiation during annealing improve shallow implanted nitrogen-vacancy centers in diamond?

Abstract

It has been reported that the conversion yield and coherence time of ion-implanted NV centers improve if the Fermi level is raised or lowered during the annealing step following implantation. Here, we investigate whether surface transfer doping and surface charging, by UV light, can be harnessed to induce this effect. We analyze the coherence times and the yield of NV centers created by ion implantation and annealing, applying various conditions during annealing. Specifically, we study coating diamond with nickel, palladium, or aluminum oxide, to induce positive surface transfer doping, as well as annealing under UV illumination to trigger vacancy charging. The metal-coated diamonds display a two times higher formation yield than the other samples. The coherence time T2 varies by less than a factor of two between the investigated samples. Both effects are weaker than previous reports, suggesting that stronger modifications of the band structure are necessary to find a pronounced effect. UV irradiation has no effect on the yield and T2 times.