ESTUDO DA TAXA DE DESOXIDAÇÃO NO REFINO SECUNDÁRIO EM AÇOS DESOXIDADOS AO SILICIO E MANGANÊS

Abstract

This work has aimed at evaluating the deoxidation characteristics for Si-Mn in Electric Arc Furnace (EAF) melt shops. A statistical methodology led to the identification of the key EAF tapping process parameters that affect Si and O evolution during secondary refining. A first order kinetic equation estimated the deoxidation constants at the beginning of the ladle furnace process. The experimental values were 5.3∙10−3 ?−1and 3.6∙10−3 ?−1. As expected, these values are higher than that estimated for the reduction of the total oxygen content based on the gas injection agitation energy, which was 1.67∙10−3 ?−1, confirming the importance of the agitation caused by tapping. A model that couples slag and metal composition evolution in special from tapping to arrival at the ladle furnace (LF) was developed. The model confirmed the presence of undissolved slag solid fraction on arrival at the LF and made reasonable prediction for the liquid phase composition. The potential, limitations and applicability of each model are discussed, aiming at defining the next steps for a complete model for ferro-alloys additions to Si-Mn steels.