Relevance of rheology on the properties of PP/MWCNT nanocomposites elaborated with different irradiation/mixing protocols

Abstract

Linear and nonlinear rheological features and electrical conductivity of two nanocomposite systems based on polypropylene/multiwall carbon nanotubes (PP/MWCNT) are investigated. The nanocomposites were irradiated with an electron beam following two different procedures. Protocol A, where the nanocomposite mixture is irradiated, and Protocol B where only the PP matrix is irradiated before mixing with MWCNT. The same irradiation dose adjusted to bring about long chain branching (LCB) but not crosslinking, is used in both types of nanocomposites. The modification of the polymer matrix viscosity caused by irradiation determines the MWCNT dispersion and therefore the rheological and percolation thresholds. Elongational flow results reveal that strain hardening, typical of irradiated PPs, is observed for the nanocomposites irradiated, but not for the nanocomposites prepared with the irradiated PP. The hypothesis of a shear flow modification that aligns the branches into the backbone, eliminating the strain hardening is considered.