Synthesis of dithiocarbamates by the one-pot three-component Markovnikov addition reaction of an amine, carbon disulfide and an alkyl vinyl ether or N-vinylpyrrolidone is reported in polyethylene glycol (PEG) under a mild and green procedure with high yields and completely regiospecific. Also, the products were used as efficient starting materials for amidoalkylation of electron-rich arenes such as naphthols and indoles.
CITATION STYLE
Halimehjani, A. Z., Dadras, A., Ramezani, M., Shamiri, E. V., Hooshmand, S. E., & Hashemi, M. M. (2015). Synthesis of dithiocarbamates by Markovnikov addition reaction in PEG and their application in amidoalkylation of naphthols and indoles. Journal of the Brazilian Chemical Society, 26(7), 1500–1508. https://doi.org/10.5935/0103-5053.20150119
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