Mechanistic analysis of photopolymerization reactions in the presence of HABI / hydrogen donor photoinitiating system

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Abstract

The comparative efficiency of two multi-component photoinitiating systems (PIS): EAB/Cl-HABI/NPG and Cl/Cl-HABI/NPG (where Cl-HABI is a bisimidazole derivative. EAB an aminobenzophenone, NPG N-phenylglycine, Cl coumarin 1) are investigated through real time FT-IR, time-resolved laser spectroscopy and steady state analytical techniques. The investigation of the excited state processes in these multi-component photoinitiating systems, the elaboration of a general picture for the mechanisms encountered in the different PIS and a discussion on the relative efficiency of these PIS are presented.

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Allonas, X., Fouassier, J. P., Obeid, H., Kaji, M., & Ichihashi, Y. (2004). Mechanistic analysis of photopolymerization reactions in the presence of HABI / hydrogen donor photoinitiating system. In Journal of Photopolymer Science and Technology (Vol. 17, pp. 35–40). Tokai University. https://doi.org/10.2494/photopolymer.17.35

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