N-Acetyl-N-[2,4-dicyano-1-(4-meth-oxy-phen-yl)-9,10-dihydro-phenanthren-3- yl]acetamide

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Abstract

In the title compound, C27H21N3O 3, the cyclo-hexa-1,3-diene ring has a screw-boat conformation, and the fused ring system is folded, the dihedral angle between the outer benzene rings being 27.61 (6)°. The N-acetyl-acetamide residue (r.m.s. deviation = 0.0935 Å) has an anti conformation and is essentially perpendicular to the benzene ring to which it is connected [dihedral angle = 89.14 (6)°]; the meth-oxy-benzene group is also twisted out of this ring [dihedral angle = 59.47 (7)°]. The three-dimensional architecture is consolidated by C-H⋯O and C-H⋯π inter-actions.

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Asiri, A. M., Faidallah, H. M., Al-Thabaiti, S. A., Ng, S. W., & Tiekink, E. R. T. (2012). N-Acetyl-N-[2,4-dicyano-1-(4-meth-oxy-phen-yl)-9,10-dihydro-phenanthren-3- yl]acetamide. Acta Crystallographica Section E: Structure Reports Online, 68(4). https://doi.org/10.1107/S160053681201210X

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