Anticorrosive performance of vinyl butyral-co-vinyl alcohol-co-vinyl acetate based copolymer adsorbed on steel surfaces. Electrochemical and AFM studies

Abstract

The copolymer film anticorrosive performance based on poly(vinyl butyral-co-vinyl alcohol-co-vinyl acetate), called in this study as PVBA, deposited by the dipping method on the carbon steel and 304L stainless steel surfaces from methanolic solution was studied by open circuit potential (OCP) measurements, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The morphological characteristics of the uncovered and covered surfaces with copolymer film, before and after corrosion were identified by atomic force microscopy (AFM). The average protection performance (P%) of PVBA adsorbed on metallic surfaces corroded in 0.9% NaCl solution reached the value of 64 ± 2% for carbon steel and 72 ± 2%, respectively, for 304L stainless steel. AFM 3D images, before corrosion, display coherently organized coatings adsorbed on the surfaces of steels, with a network characteristic, more obviously in the case of 304L stainless steel than that of carbon steel. After corrosion, AFM shows that the surface upper-layers preserve their features, suggesting that the coating remains anchored to the metal surface for a long time, but the polymer swelling in NaCl solution causes the relative detachment of the film from the substrate, with the formation of some free areas on which the oxidation processes can be accelerated, leading to PVBA anticorrosive performance disturbance.