Abstract
A new class of alkaline anion-exchange membranes containing mobile ion shuttles is developed. It is achieved by threading ionic linear guests into poly(crown ether) hosts via host-guest molecular interaction. The thermal- and pH-triggered shuttling of ionic linear guests remarkably increases the solvation-shell fluctuations in inactive hydrated hydroxide ion complexes (OH-(H2O)4) and accelerates the OH- transport.
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Ge, X., He, Y., Guiver, M. D., Wu, L., Ran, J., Yang, Z., & Xu, T. (2016). Alkaline Anion-Exchange Membranes Containing Mobile Ion Shuttles. Advanced Materials, 28(18), 3467–3472. https://doi.org/10.1002/adma.201506199
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