Profluorescent verdazyl radicals - synthesis and characterization

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Abstract

The synthesis and characterization of various 6-oxo-verdazyl radicals and their diamagnetic styryl radical trapping products are presented. It is shown that styryl radical trapping products derived from N-phenyl verdazyls show fluorescence whereas the N-methyl congeners are non-fluorescent. In the parent N-phenyl verdazyls fluorescence is fully quenched which renders these compounds highly valuable profluorescent radical probes.

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Matuschek, D., Eusterwiemann, S., Stegemann, L., Doerenkamp, C., Wibbeling, B., Daniliuc, C. G., … Studer, A. (2015). Profluorescent verdazyl radicals - synthesis and characterization. Chemical Science, 6(8), 4712–4716. https://doi.org/10.1039/c5sc00724k

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