The autoprotolysis constants of several water-N,N-dimethylformamide mixtures were determined. The acid dissociation constants of formic, acetic, propionic, n-butyric, isobutyric, n-valeric, isovaleric, 2-methylbutyric and trimethylacetic acids were evaluated in the same media by potentiometric titration. Empirical equations for the calculation of autoprotolysis constants and acid dissociation constants at 25 ° C in the mixed solvents are proposed. Approximate solvation numbers were obtained by multiple linear regression analyses of pK. values.
CITATION STYLE
Meakin, P. (1986). Computer Simulation of Growth and Aggregation Processes. In On Growth and Form (pp. 111–135). Springer Netherlands. https://doi.org/10.1007/978-94-009-5165-5_7
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