Abstract
The synthesis and crystallographic characterization of a complex possessing a well-defined {2Fe3S(μ-H)} core gives access to a paramagnetic bridging hydride with retention of the core geometry. Chemistry of this 35-electron species within the confines of a thin-layer FTIR spectro-electrochemistry cell provides evidence for a unprecedented super-reduced FeI(μ-H)FeI intermediate.
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Jablonskyte, A., Wright, J. A., Fairhurst, S. A., Webster, L. R., & Pickett, C. J. (2014). [FeFe] hydrogenase: Protonation of {2Fe3S} systems and formation of super-reduced hydride states. Angewandte Chemie - International Edition, 53(38), 10143–10146. https://doi.org/10.1002/anie.201406210
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