Bis{μ-4,4′,6,6′-tetra-tert-butyl-2,2′-[N-(2- oxidoethyl)iminodimethylene]diphenolato}dialuminium(III)

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Abstract

The title compound, [Al2(C32H48NO 3)2], exists as a dimer with bridging ethoxide groups. It was isolated from a reaction mixture of the parent ligand and trimethyl-aluminium in tetra-hydro-furan. The geometry around the Al III atom is a slightly distorted trigonal-bipyramid, typical of atrane derivatives.

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Hemmingson, S. L., Stevens, A. J., Tanski, J. M., & Getzler, Y. D. Y. L. (2010). Bis{μ-4,4′,6,6′-tetra-tert-butyl-2,2′-[N-(2- oxidoethyl)iminodimethylene]diphenolato}dialuminium(III). Acta Crystallographica Section E: Structure Reports Online, 66(8). https://doi.org/10.1107/S1600536810027212

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