Scanning electron microscopy and molecular dynamics of surfaces of growing and ablating hexagonal ice crystals

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Abstract

We present the first clearly resolved observations of surfaces of growing and ablating hexagonal ice crystals using variable-pressure scanning electron microscopy. The ice surface develops trans-prismatic strands, separated from one another by distances of 5ĝ€"10 μm. The strands are present at a wide range of supersaturations, but are most pronounced at temperatures near the frost point. Pyramidal facets consistent with Miller-Bravais indices of 10 1 1, and possibly also 20 2 1, are associated with ice growth under these conditions. A molecular-dynamics model of a free-standing iceIh nanocolumn containing 8400 water molecules does not develop trans-prismatic strands, suggesting these features originate at larger spatial or temporal scales. The possible relevance of these surface features to cirrus ice is discussed. © 2010 Author(s).

Figures

  • Fig. 1. VP-SEM images of growing ice crystals. The black background is the copper substrate.
  • Fig. 2. Hexagonal ice crystal in an early stage of growth. The first micrograph was taken seconds after the crystal was noticed, the second was taken 32 s later.
  • Fig. 3. Growth and ablation sequences. (A) Low magnification view of a growing ice crystal. (B) View of the same crystal after ∼15 min of ablation conditions. (C–F) Higher magnification sequence showing growth at the prismatic edge at the center of A, taken at intervals of ∼30 s. (G–I) Higher magnification sequence showing ablation at the same prismatic edge, also at intervals of ∼30 s.
  • Fig. 4. Ablation onset temperature as a function of time for a typical VP-SEM session.
  • Fig. 5. Supersaturation values at the examination stage for a typical VP-SEM session for nominal stage temperatures (Ts in Eq. 1). Ablation onset temperatures (Tf in Eq. 1) are taken from Fig. 4. The −45 ◦C curve is extrapolated to point B, since at that point in the session the examination stage could not be cooled enough to induce another growth transition.
  • Fig. 6. Re-growth sequences of a previously ablated crystal. Scale bars in the first image of each series apply to all images in the series. (A–D) View of the prismatic edge during initial regrowth of an ablated crystal at intervals of ∼45 seconds. (E–H) Regrowth on the same crystal a few minutes later, at lower magnification, at intervals of ∼90 s. (I–L) Final regrowth of the ablated edge, at higher magnification, at intervals of ∼45 seconds.
  • Fig. 7. Detail showing the measurement of the prismatic-topyramidal angle, θ , for a crystal imaged by VP-SEM.
  • Fig. 8. Integrated number density of oxygen atoms of the freestanding nanocolumn of 8400 water molecules, as a function of distance along the crystallographic c-axis (z), simulated by molecular dynamics. Time=0 refers to the moment at which basal surfaces were exposed to vacuum. The inset shows the mean molecular potential energy over time.

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CITATION STYLE

APA

Pfalzgraff, W. C., Hulscher, R. M., & Neshyba, S. P. (2010). Scanning electron microscopy and molecular dynamics of surfaces of growing and ablating hexagonal ice crystals. Atmospheric Chemistry and Physics, 10(6), 2927–2935. https://doi.org/10.5194/acp-10-2927-2010

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