Abstract
(Figure Presented) Turbocharged! A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent "(iPr2N) MgCI· LiCl" (see structure; blue N, red O, green Mg, yellow Cl, black C) separates into several charged ate species in dynamic exchange with each other in THF solution as determined by a combination of EXSY and DOSY NMR studies. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
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Armstrong, D. R., García-Álvarez, P., Kennedy, A. R., Mulvey, R. E., & Parkinson, J. A. (2010). Diisopropylamide and TMP turbo-grignard reagents: A structural rationale for their contrasting reactivities. Angewandte Chemie - International Edition, 49(18), 3185–3188. https://doi.org/10.1002/anie.201000539
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