Abstract
Reaction of [AuCl3(CNR1)] (R1 = Xyl, Cy, (S)-CHMePh) with amines unexpectedly proceeds via the redox pathway giving gold(i)-isocyanides and imines, while the addition of benzophenone hydrazone to the isocyanide ligand in [AuCl3(CNR1)] at RT leads to short-lived gold(iii) acyclic diaminocarbene complexes [AuCl3{C(NHNCPh2)NHR1}].
Cite
CITATION STYLE
Anisimova, T. B., Kinzhalov, M. A., Guedes Da Silva, M. F. C., Novikov, A. S., Kukushkin, V. Y., Pombeiro, A. J. L., & Luzyanin, K. V. (2017). Addition of: N -nucleophiles to gold(III)-bound isocyanides leading to short-lived gold(III) acyclic diaminocarbene complexes. New Journal of Chemistry, 41(9), 3246–3250. https://doi.org/10.1039/c7nj00529f
Register to see more suggestions
Mendeley helps you to discover research relevant for your work.
