Abstract
Bis(methylammonium) octaantimony(III) dodecasulfide persulflde, (CH 3NH3)2[Sb8S12(S 2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulflde bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb⋯S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-l,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains. © 2005 International Union of Crystallography.
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CITATION STYLE
Lees, R. J. E., Powell, A. V., & Chippindale, A. M. (2005). Methylammonium antimony sulfide. Acta Crystallographica Section C: Crystal Structure Communications, 61(12). https://doi.org/10.1107/S0108270105032361
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