Efficient production of n‐butyl levulinate fuel additive from levulinic acid using amorphous carbon enriched with oxygenated groups

Abstract

The aim of this study was to develop an effective carbonaceous solid acid for synthesizing green fuel additive through esterification of lignocellulose‐derived levulinic acid (LA) and n‐butanol. Two different sulfonated carbons were prepared from glucose‐derived amorphous carbon (GC400) and commercial active carbon (AC400). They were contrastively studied by a series of characterizations (N2 adsorption, X‐ray diffraction, elemental analysis, transmission electron microscopy, Fourier transform infrared spectroscopy and NH3 temperature programmed desorption). The results indicated that GC400 possessed stronger acidity and higher –SO3H density than AC400, and the amorphous structure qualified GC400 for good swelling capacity in the reaction solution. Assessment experiments showed that GC400 displayed remarkably higher catalytic efficiency than AC400 and other typical solid acids (HZSM‐5, Hβ, Amberlyst‐15 and Nafion‐212 resin). Up to 90.5% conversion of LA and 100% selectivity of n‐butyl levulinate could be obtained on GC400 under the optimal reaction conditions. The sulfonated carbon retained 92% of its original catalytic activity even after five cycles.