3-{4-[(2-Hydroxybenzylidene)amino]-3-methyl-5-sulfanylidene-4, 5-dihydro-1H-1,2,4-triazol-1-yl}-1,3-diphenylpropan-1-one

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Abstract

There are two crystallographically independent molecules (A and B) in the asymmetric unit of the title compound, C 25H 22N 4O 2S, with almost identical molecular conformations. The hydroxyphenyl ring plane and the 1,2,4-triazole ring form dihedral angles of 17.1 (2) and 7.4 (2)° in A and B, respectively. The dihedral angles between 1,2,4-triazole ring and the other two phenyl rings are 89.6 (3) and 83.3 (2)° in molecule A, and 89.2 (3) and 82.2 (2)° in molecule B. One intramolecular O - H⋯N hydrogen bond is present in each molecule. Weak intermolecular C - H⋯O hydrogen bonds consolidate the crystal packing.

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Wang, W., Gao, Y., Zhang, J. J., Jia, X. Y., & Wu, W. P. (2011). 3-{4-[(2-Hydroxybenzylidene)amino]-3-methyl-5-sulfanylidene-4, 5-dihydro-1H-1,2,4-triazol-1-yl}-1,3-diphenylpropan-1-one. Acta Crystallographica Section E: Structure Reports Online, 67(9). https://doi.org/10.1107/S1600536811034878

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