Abstract
Electrochemical oxidation of 5-hydroxymethylfurfural (HMF) is a promising synthetic route for 2,5-furandicarboxylic acid (FDCA) production. Here, we prepared a nickel(ii)-modified covalent-organic framework (COF) film TpBpy-Ni@FTO for HMF electrooxidation. With a high conversion of HMF (96%), TpBpy-Ni@FTO afforded a 58% FDCA yield. This work underlines the great potential of COF-based materials in electrocatalysis.
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CITATION STYLE
Cai, M., Ding, S., Gibbons, B., Yang, X., Kessinger, M. C., & Morris, A. J. (2020). Nickel(ii)-modified covalent-organic framework film for electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF). Chemical Communications, 56(92), 14361–14364. https://doi.org/10.1039/d0cc02206c
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