Morphology and properties of silica-based coatings with different functionalities for Fe3O4, ZnO and Al2O3 nanoparticles

Abstract

A facile single-step method for obtaining 2-3 nm thick silsesquioxane coatings on metal oxide nanoparticles using different carbon-functional silane precursors is presented. Iron oxide nanoparticles with 8.5 nm in diameter were used as a model to evaluate the possibilities of forming different uniform carbon-functional coatings, ranging from hydrophobic to hydrophilic in character. Electron microscopy showed that all the coated nanoparticles could be described as core-shell nanoparticles with single Fe3O4 cores and carbon-functional silsesquioxane shells, without any core-free silicone oxide phase. Steric factors strongly influenced the deposited silicon oxide precursors with octyl-, methyl- or aminopropyl functionalities, resulting in coating densities ranging from 260 to 560 kg m-3. The methyl-functional coatings required several layers of silsesquioxane, 3-4, to build up the 2 nm structures, whereas only 1-2 layers were required for silsesquioxane with octyl groups. Pure silica coatings from tetraethoxysilanes were however considerably thicker due to the absence of steric hindrance during deposition, allowing the formation of 5-7 nm coatings of ca. 10 layers. The coating method developed for the iron oxide nanoparticles was generic and successfully transferred and up-scaled 30 and 325 times (by volume) to be applicable to 25 nm ZnO and 45 nm Al2O3 nanoparticles.