Electrodeposited CoNiP Films with Perpendicular Magnetic Anisotropy

Abstract

CoNiP alloy films have been grown by electrodeposition from a chloride bath under galvanostatic control. Film growth, structure, composition, magnetic properties, and morphology have been found to depend significantly on deposition current density. Hard magnetic films were successfully grown at the current density of 7 mA cm2 with thickness up to 10 μm, at which a perpendicular coercivity of 188 kAm was achieved. The magnetic hardness and perpendicular anisotropy of these films are the combined result of a microstructure composed of columnar grains and of a hexagonal phase oriented with the c axis perpendicular to the film plane. Preliminary investigations of magnetization reversal processes suggest the presence of pinning sites located probably at grain boundaries. © 2007 The Electrochemical Society.