Effect of oxide additions on the polymorphism of tantalum pentoxide. III. ""Stabilization"" of the low temperature structure type

  • Roth R
  • Waring J
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Abstract

The high temperature, apparently tetragonal, polymorph of tantalum pentoxide can be obtained at room temperature by quenching a specimen containing 2-5 mole percent of the following oxides: SnO2, Ga2O3, Cr2O3, Fe2O3, Sc2O3, or MgO. All the x-ray patterns can be indexed on a body centered tetragonal cell with a ? 3.830 ?, c ? 35.68 ?. However, P2O5, V2O5, Nb2O5, ZrO2, Lu2O3, NiO, or ZnO do not stabilize the tetragonal form at room temperature. Single crystals of scandium 'stabilized' Ta2O5, have been grown by the Czochralski technique.

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Roth, R. S., & Waring, J. L. (1970). Effect of oxide additions on the polymorphism of tantalum pentoxide. III. “‘Stabilization’” of the low temperature structure type. Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry, 74A(4), 485. https://doi.org/10.6028/jres.074a.038

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