Effects of the Basicity on the Comelting Conditions of Municipal Solid Waste Incinerator Fly Ash and Sewage Sludge Ash

Abstract

In this study, the effects of the basicity on the pouring point of the municipal solid waste incinerator fly ash-sewage sludge ash mixture is investigated. Four kinds of sewage sludge ash, which were collected from several primary and secondary sewage treatment plants and were produced by different processes and sludge conditioning alternatives, were used as modifiers. The results indicate that the pouring point of the mixture increased with increasing basicity, within the range of 0.65–1.90. The pouring point is affected by the contents of the mixtures (CaO, SiO2, Al2O3, and the flux). It is suggested that an increase in the CaO content tends to raise the pouring point, whereas an increase in the SiO2 and/or the Al2O3 contents cause as adverse reaction. The prediction equation, obtained by multilinear regression (significant level is 0.05), is as follows: pouring temperature =1189.6 + 4.19CaO-0.96 SiO2-4.33 Al2O3 (R2 = 0.91). In general, the pouring point decreased when the basicity was <1. The pouring point apparently increased when the basicity was>1.2. The regression squares for the different basicities were between 0.84 and 0.91. From these relationships, we note that a basicity index of 5 gave the best R2 (0.91). From the results of this study, it can be concluded that the modification of the basicity of the fly ash by the addition of sewage sludge ash to lower the pouring point is feasible and leads to a more energy-efficient melting process. In addition, these synthetic slags have a good pozzolanic reactive activity. © 2006 Air & Waste Management Association.