Adsorption of Methyl Orange from an Aqueous Solution onto a BPPO-Based Anion Exchange Membrane

Abstract

In this research, the development of a novel brominated poly(2,6-dimethyl-1,4-phenylene oxide) (BPPO)-based homogeneous anion exchange membrane (AEM) via the solution casting method was reported. Fourier transform infrared spectroscopy was used to confirm the successful development of the BPPO-based AEM. The prepared AEM showed excellent thermal stability. It exhibited an ion exchange capacity of 2.66 mg/g, a water uptake (WR) of 68%, and a linear swelling ratio of 31%. Methyl orange (MO), an anionic dye, was used as a model pollutant to evaluate the ion exchange ability of the membrane. The adsorption capacity of MO increased with the increase in contact time, membrane dosage (adsorbent), temperature, and pH while declined with the increase in initial concentration of MO in an aqueous solution and molarity of NaCl. Adsorption isotherm study showed that adsorption of MO was fitted well to the Freundlich adsorption isotherm because the value of the correlation coefficient (R2= 0.974) was close to unity. Adsorption kinetics study showed that adsorption of MO fitted well to the pseudo-second-order kinetic model. Adsorption thermodynamics evaluation represented that adsorption of MO was an endothermic (ΔH° = 18.72 kJ/mol) and spontaneous process. The AEM presented a maximum adsorption capacity of 18 mg/g. Moreover, the regeneration of the prepared membrane confirmed its ability to be utilized for three consecutive cycles. The developed BPPO-based AEM was an outstanding candidate for adsorption of MO from an aqueous solution.