Simple, Rapid, and Cost Effective: A Screening Method for 14C Analysis of Small Carbonate Samples

Abstract

We have developed a simple, rapid method to screen carbonates for survey applications, which provides radiocarbon dates with decreased precision at lower cost. The method is based on previous work by Longworth et al. (2011) and involves mixing pulverized CaCO3 with Fe powder, followed by pressing into aluminum target holders for direct 14C accelerator mass spectrometry (AMS) measurements. An optimum beam current averaging ~10% of those produced by >0.7 mg C graphite targets was obtained for carbonate samples of 0.3-0.5 mg (0.04-0.06 mg C). The precision of the method was evaluated by measuring triplicates of 14C reference materials, as well as by comparing results from this rapid method with results from high-precision AMS measurements on graphite (typically 0.2-0.3%). Measurement reproducibility was ~1.8% (1σ) for samples <10 ka BP, and it increased drastically for older samples. However, t tests on paired samples resulted in p values greater than 0.05, indicating a good correlation between this survey method and the conventional one. An average blank (calcite) of 0.0075 Fm (~39 ka BP) was achieved. The simplicity of the technique allowed us to process and measure 72 deep-sea coral samples in less than 25 hr. © 2013 by the Arizona Board of Regents on behalf of the University of Arizona.