Vibrational Energy Relaxation in Liquid-to- Supercritical Ammonia Studied by Femtosecond Mid-Infrared Spectroscopy

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Abstract

Femtosecond mid-infrared spectroscopy was used to explore the vibrational energy relaxation dynamics of NH2D in fluid NH3. The density and temperature dependence of the ND-stretching lifetime suggests that hydrogen bonding is unimportant for vibrational energy transfer.

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Lindner, J., Schäfer, T., Schwarzer, D., & Vöhringer, P. (2009). Vibrational Energy Relaxation in Liquid-to- Supercritical Ammonia Studied by Femtosecond Mid-Infrared Spectroscopy. In Springer Series in Chemical Physics (Vol. 92, pp. 466–468). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-540-95946-5_151

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