Utilizing CO2 as a Reactant for C3 Oxygenate Production via Tandem Reactions

Abstract

One possible solution to closing the loop on carbon emissions is using CO2 as the carbon source to generate high-value, multicarbon products. In this Perspective, we describe four tandem reaction strategies for converting CO2 into C3 oxygenated hydrocarbon products (i.e., propanal and 1-propanol), using either ethane or water as the hydrogen source: (1) thermocatalytic CO2-assisted dehydrogenation and reforming of ethane to ethylene, CO, and H2, followed by heterogeneous hydroformylation, (2) one-pot conversion of CO2 and ethane using plasma-activated reactions in combination with thermocatalysis, (3) electrochemical CO2 reduction to ethylene, CO, and H2, followed by thermocatalytic hydroformylation, and (4) electrochemical CO2 reduction to CO, followed by electrochemical CO reduction to C3 oxygenates. We discuss the proof-of-concept results and key challenges for each tandem scheme, and we conduct a comparative analysis of the energy costs and prospects for net CO2 reduction. The use of tandem reaction systems can provide an alternative approach to traditional catalytic processes, and these concepts can be further extended to other chemical reactions and products, thereby opening new opportunities for innovative CO2 utilization technologies.