TRANSFORMATION OF VERMICULITE TO PEDOGENIC MICA BY FIXATION OF POTASSIUM AND AMMONIUM IN A SIX-YEAR FIELD MANURE APPLICATION EXPERIMENT

Abstract

In a field experiment in which heavy applications of liquid dairy manure were added annually for 6 yr to a vermiculite-containing corn-cropped sandy clay loam soil (Mountain series), fixation potential and X-ray diffraction analyses were done to determine if fixation of added K + and NH 4 + had occurred and clay mineralogical changes could be detected. Of the 850 kg K + and the 460 kg NH 4 + added per hectare each year, approximately 28% of the K + and 24% of the NH 4 + remained fixed. This caused a marked increase in the 1.0-nm peak at the expense of the 1.4-nm peak due to collapse of vermiculite layers to form pedogenic mica. Thus, changes in soil management, specifically in fertilizer practices, can result in significant changes in clay mineralogy within a short period of time. Such changes are agronomically important and should be taken into account in the interpretation of clay mineralogical data. Key words: Potassium and ammonium fixation, vermiculite to pedogenic mica transformation, liquid manure application