Investigation of the influence of impurities on the ring-opening polymerisation of L-Lactide from biogenous feedstock

Abstract

In order to use a L-lactide monomer that is derived from fermentation processes it is necessary to understand, how the polymerisation process is influenced by impurities which derive from the production process. We have selected a group of likely contaminants and added them at various concentrations to the polymerisation of L-lactide using tin (II)-2-ethylhexanoate as catalyst and 2-methoxyethanol as initiator. The effect of impurities onto the global properties of the polymers such as glass transition temperature, melting point and molecular mass distribution were investigated and NMR and MALDI mass spectrometry were used to identify structural changes within the polymers. Thus, it could be shown that in reference experiments cyclic polymers and linear polymers with different starting groups are formed. Addition of ethanol and sodium carbonate showed the strongest influence on molecular masses as well as polymer structures, which could be elucidated by interpretation of the MALDI mass spectra and NMR data.