Molecular Reorientation of Methanol in Mixtures with Carbon Tetrachloride

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Abstract

Proton and oxygen-17 nmr relaxation ratcsof CD3l7OH as well as deuteron nmr relaxation rates of CH3OD were measured in mixtures with carbon tetrachloride at different compositions and temperatures, By varying the 17O-content different contributions to the proton relaxation rate could be separated and from the 170-Hdipolar interaction contribution the correlation time τ2OHOF the OH bond was determined. Using these correlation times the composition dependencc of the deuterium and oxygen-17 quadrupole coupling constants of methanol was derived. A strong variation of the coupling constants over the measured composition range is evident. © 1992, Verlag der Zeitschrift für Naturforschung, All rights reserved.

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Gill, D. S., & Zeidler, M. D. (1992). Molecular Reorientation of Methanol in Mixtures with Carbon Tetrachloride. Zeitschrift Fur Naturforschung - Section A Journal of Physical Sciences, 47(7–8), 857–864. https://doi.org/10.1515/zna-1992-7-810

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